how do you pin to start in windows 10 from a login script/kixtart?

there are things i want to setup a user environment for when I deploy a new pc.

a) word/excel/powerpoint/outlook (2010,2013,2016 whatever is installed)
b) remote desktop connection

and make sure they are pinned as the first items rather than currently where you manually pin them, they are below all the microsoft junk.