The problem you are likely running into is kix is a 32 bit process, and you are running it on a 64bit OS. Windows (by default) redirects 32bit processes to look in %systemroot%\syswow64 instead of system32, and makes it appear as though files that are most definitely there, are not.

You have a couple of options:
$RC=setoption("Wow64FileRedirection","off")

or use sysnative, ie
 Code:
if exist("%systemroot%\sysnative\drivers\etc\hosts.")
  "found"
else
  "not found"
endif


More info on both of these suggestions can be found in the following thread:
http://www.kixtart.org/forums/ubbthreads.php?ubb=showflat&Number=187063#Post187063
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