I presume here a quote is missing:
Code:

Select
Case ($LibraryPrinterRadioButton.Checked = "False") AND ($LibraryPrinterCheckBox.CheckState = -1)
AddPrinter("10.48.55.72","Lexmark T640","\\s096-a290-01\sch030$\printers\t640.inf","Library Printer",0)
Case ($LibraryPrinterRadioButton.Checked = "True") AND ($LibraryPrinterCheckBox.CheckState = -1)
AddPrinter("10.48.55.72","Lexmark T640","\\s096-a290-01\sch030$\printers\t640.inf","Library Printer",1)
Case ($ComputerLabRadioButton.Checked = "False") AND ($ComputerLabCheckBox.CheckState = -1)
AddPrinter("10.48.55.71","Lexmark T640","\\s096-a290-01\sch030$\printers\t640.inf","Computer Lab Printer",0)
Case ($ComputerLabRadioButton.Checked = "True") AND ($ComputerLabCheckBox.CheckState = -1)
AddPrinter("10.48.55.71","Lexmark T640","\\s096-a290-01\sch030$\printers\t640.inf","Computer Lab Printer",1)
Case $OfficePrinterCheckBox.CheckState = -1
AddPrinter("10.48.55.70","Lexmark T640","\\s096-a290-01\sch030$\printers\t640.inf","Office Printer",0)
EndSelect